Revisited Synthesis of Trispyrazolylborate Aluminum Halides

Suban Kundu, Raju Chambenahalli, Alex P. Andrews and Ajay Venugopal

European Journal of Inorganic Chemistry

2024

 

Quest for Active Species in Al/B-Catalyzed CO2 Hydrosilylation

S K Bisht,  D Sharma, R Kannan, T Rajeshkumar, L Maron,  A Venugopal

Inorganic Chemistry 62 (37), 14828–14832

2023 

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From Sn(II) to Sn(IV): Enhancing Lewis Acidity Via Oxidation

Rini Prakash, Jerin Joseph, Alex P. Andrews, Babu Varghese, and Ajay Venugopal

Inorganic Chemistry 62 (37), 14828–14832

2023 

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Mechanistic Investigations on Bismuth Catalysed Reduction of Ketones and Phosphine Oxides

A Benny, D Sharma, Ankur, T Rajeshkumar, L Maron, A Venugopal

Chemistry–A European Journal 29, e202300588

2023

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Reactivity of a quasi-four-coordinate butylmagnesium cation

Ankur, D Sharma, AP Andrews, A Venugopal

Dalton Transactions 52 (6), 1533-1537

2023

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Computational Insights on Periodicity in Bonding and Lewis Acidity and Basicity of the p‐Block Trispyrazolylborate Complexes

R Prakash, A Mohamed, ED Jemmis, A Venugopal

European Journal of Inorganic Chemistry 26 (2), e202200585

2023

 

Crystallographic evidence for a continuum and reversal of roles in primary–secondary interactions in antimony Lewis acids: applications in carbonyl activation

D Sharma, A Benny, R Gupta, ED Jemmis, A Venugopal

Chemical Communications 58 (78), 11009-11012

2022

 

Magnesium Complexes in Organic Synthesis

Ankur, S Kundu, S Banerjee, A Venugopal

Elsevier

2022

 

[(Me6TREN)MgOCHPh2][B(C6F5)4]: A Model Complex to Explore the Catalytic Activity of Magnesium Alkoxides in Ketone Hydroboration

Ankur, R Kannan, R Chambenahalli, S Banerjee, Y Yang, L Maron, A Venugopal

European Journal of Inorganic Chemistry 2021 (45), 4632-4638

2021

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Reversing Lewis acidity from bismuth to antimony

D Sharma, S Balasubramaniam, S Kumar, ED Jemmis, A Venugopal

Chemical Communications 57 (71), 8889-8892

2021

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Cationic Zinc Hydride Catalyzed Carbon Dioxide Reduction to Formate: Deciphering Elementary Reactions, Isolation of Intermediates, and Computational Investigations

R Chambenahalli, RM Bhargav, KN McCabe, AP Andrews, F Ritter, A Venugopal

Chemistry–A European Journal 27 (26), 7391-7401

2021

 

Electrophilic Organobismuth Dication Catalyzes Carbonyl Hydrosilylation

R Kannan, S Balasubramaniam, S Kumar, R Chambenahalli, ED Jemmis, A Venugopal

Chemistry–A European Journal 26 (56), 12717-12721

2020  (Cover Feature) https://doi.org/10.1002/chem.202002006

 

trans‐Influence in Heavy Main Group Compounds: A Case Study on Tris(pyrazolyl)borate Bismuth Complexes

S Balasubramaniam, S Kumar, AP Andrews, ED Jemmis, A Venugopal

European Journal of Inorganic Chemistry 2020 (26), 2530-2536

2020

 

Probing the Lewis acidity of heavier pnictogen trichlorides

JA Johnson, A Venugopal

Journal of Chemical Sciences 131, 1-6

2019

 

A dicationic bismuth (III) lewis acid: catalytic hydrosilylation of olefins

S Balasubramaniam, S Kumar, AP Andrews, B Varghese, ED Jemmis, A Venugopal

European Journal of Inorganic Chemistry 2019 (28), 3265-3269

2019  (Front Cover) 

 

Bismuth (III) dication trapped on a chlorobismuthate

S Balasubramaniam, B Varghese, A Venugopal

Journal of Coordination Chemistry 72 (8), 1417-1423

2019

 

Organoaluminum cations for carbonyl activation

R Kannan, R Chambenahalli, S Kumar, A Krishna, AP Andrews, A Venugopal

Chemical Communications 55 (97), 14629-14632

2019

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Amidomagnesium cations

S Banerjee, Ankur, AP Andrews, B Varghese, A Venugopal

Dalton Transactions 48 (21), 7313-7319

2019

 

Terminal hydridozinc cation

R Chambenahalli, AP Andrews, F Ritter, J Okuda, A Venugopal

Chemical Communications 55 (14), 2054-2057

2019

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A disguised hydride in a butylmagnesium cation

S Banerjee, Ankur, A Andrews, A Venugopal

Chemical Communications 54 (45), 5788-5791

2018

 

Consequence of Ligand bite angle on bismuth lewis acidity

R Kannan, S Kumar, AP Andrews, ED Jemmis, A Venugopal

Inorganic Chemistry 56 (16), 9391-9395

2017

 

Neutral and Cationic β‐Ketoiminato Bismuth Complexes

JA Johnson, A Ashokan, AK Chalana, AP Andrews, A Venugopal

Zeitschrift für anorganische und allgemeine Chemie 643 (9), 607-611

2017

 

2, 6‐Diisopropylanilinium Bromobismuthates

S Pandey, A Nair, AP Andrews, A Venugopal

European Journal of Inorganic Chemistry 2017 (4), 798-804

2017

 

Manifestation of helicity in one-dimensional iodobismuthate

S Pandey, AP Andrews, A Venugopal

Dalton Transactions 45 (21), 8705-8707

2016

 

Molekulare Seltenerdmetallhydride in Nicht‐Cyclopentadienyl‐Umgebungen

W Fegler, A Venugopal, M Kramer, J Okuda

Angewandte Chemie 127 (6), 1744-1757

2015

 

Molecular Rare‐Earth‐Metal Hydrides in Non‐Cyclopentadienyl Environments

W Fegler, A Venugopal, M Kramer, J Okuda

Angewandte Chemie International Edition 54 (6), 1724-1736

2015

 

Structurally characterized α-diimine complexes of s-and p-block elements

A Raghavan, A Venugopal

Journal of Coordination Chemistry 67 (15), 2530-2549

2014

 

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